Synthesis and Properties of Two Fe(III) Coordination Polymers Based on 2-Amino-4-methylthiazole, 2-Mercaptobenzothiazole and Aromatic Polycarboxylate

Maged S. Al-Fakeh1,2,*, Nesrine Amiri3, Ahmed N. Al-Hakemi1,4, Saeed El-Sayed Saeed1 and Abuzar E.A.E. Albadri1

1Chemistry Department, College of Science, Qassim University, Buraidah-51452, Saudi Arabia

2Taiz University, Taiz, Yemen

3Laboratory of Physico-Chemistry of Materials, University of Monastir, Avenue of the Environment, 5019 Monastir, Tunisia

4Chemistry Department, College of Science, Ibb University, Yemen

*Corresponding author: E-mail: m.alfakeh@qu.edu.sa

Abstract

Two of coordination polymers of the general formula [Fe(BDC)(AMTZ)Cl]·2H2O and [Fe(BDC)(MBT)Cl]·H2O, BDC = 1,4-benzenedicarboxylic acid, AMTZ = 2-amino-4-methyl-thiazole and MBT = 2-mercaptobenzothiazole, have been synthesized and characterized. Structure of both coordination polymers has been evaluated on the basis of elemental analysis, thermal, FT-IR, UV-vis spectra and the charges been carried by the atoms, caused a dipole moment of 2.4346 debye and total energy -382 × 103 Kcal mol-1. Biological activity of the two synthesized complexes was tested against some fungal and bacterial strains.

Keywords

Coordination polymers, Properties, Iron(III) organic frameworks and biological activity.

   View Article PDF File Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.