Template Synthesis and Characterization of Transition Metal Complexes of 13, 15 and 17-Membered Tetraamide Macrocyclic Disubstituted Dimethyl Tetrasubstituted Tetraazacycloalka Tetrasubstituted Tetraene Disubstiuted Diol

B. Vimala1, S.R. Jayapradha2 and A. Selvan2,*

1Department of Chemistry, Mother Teresa Women′s University, Kodaikanal-624102, India

2Department of Chemistry, Government Arts College for Women, Nilakottai-624208, India

*Corresponding author: E-mail: selvamithu6970@gmail.com

Abstract

A series of new transition metal complexes [ML(Ln)Cl2] where Ln = L13, L15 and L17 (L(13) = 11,13-dimethyl-1,4,7,10-tetraazacyclotrideca-4,6,10,13-tetraene-5,6-diol, L(15) = 9,11-dimethyl-1,4,8,12-tetraazacyclopentadeca-1,3,8,11-tetraene-2,3-diol and L(17) = 10,12-dimethyl-1,4,9,13-tetraazacycloheptadeca-1,3,9,12-tetraene-2,3-diol) and M = Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) have been synthesized by template method. All the synthesized complexes were characterized by IR, UV, ESR, X-ray microanalysis, elemental analysis, thermal studies and magnetic susceptibilities and the geometry of the complexes found to be octahedral.

Keywords

Coordination complexes, Macrocyclic ligand, Schiff base, Polyazamacrocycles.

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